Marie Louise is off to Parma looking a little unkempt in this portrait. Her dress has a pleated bodice and vee waistline suggesting early 30s.
Empress Marie Louise, Empress of France, second wife of Napoleon
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Portrait of Marie Louise, Empress of France, 1812 — Google Arts
Marie Louise, Empress of the French, c1830. The daughter of
Marie Louise, Duchess of Parma - Wikipedia
Image of Portrait of Marie Louise, Duchess of Parma (Vienna, 1791
Napoléon Did That — Marie Louise Habsburg, Empress of the French
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Ep 229 Marie Louise: Napoleon's Second Empress
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Maria Luigia of Parma - PALAZZO PITTI